SUPELCO INC -- 47989, TCLP BSE NEUTRAL DICHLOROBENZENE (SUPP DATA) -- 6630-00N066611 
=====================  Product Identification  =====================

Product ID:47989, TCLP BSE NEUTRAL DICHLOROBENZENE (SUPP DATA)
MSDS Date:09/27/1993
FSC:6630
NIIN:00N066611
=== Responsible Party ===
Company Name:SUPELCO INC
Address:SUPELCO PARK
City:BELLEFONTE
State:PA
ZIP:16823-0048
Country:US
Info Phone Num:814-359-3441
Emergency Phone Num:814-359-3441
CAGE:54968
=== Contractor Identification ===
Company Name:SIGMA-ALDRICH INC.
Address:3050 SPRUCE STREET
Box:14508
City:ST. LOUIS
State:MO
ZIP:63103
Country:US
Phone:314-771-5765/414-273-3850X5996
CAGE:54968

=============  Composition/Information on Ingredients  =============

Ingred Name:BENZENE, HEXACHLORO-; (HEXACHLOROBENZENE) (SARA 313)
    (CERCLA) LD50(ORAL,RAT):10000 MG/KG
CAS:118-74-1
RTECS #:DA2975000
Fraction by Wt: 0.1%
OSHA PEL:N/K 
ACGIH TLV:N/K 
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:ETHANE, HEXACHLORO-; (HEXACHLOROETHANE) (SARA 313) (CERCLA)
    LD50(ORAL,RAT):4460 MG/KG
CAS:67-72-1
RTECS #:KI4025000
Fraction by Wt: 0.1%
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 1 PPM, A2
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:BENZENE, P-DICHLORO-; (P-DICHLOROBENZENE) (SARA 313)
    (CERCLA) LD50(ORAL,RAT):500 MG/KG
CAS:106-46-7
RTECS #:CZ4550000
Fraction by Wt: 0.1%
OSHA PEL:75 PPM
ACGIH TLV:10 PPM, A3
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS

Ingred Name:TOLUENE, 2,4-DINITRO-; (2,4-DINITROTOLUENE) (SARA 313)
    (CERCLA) LD50(ORAL,RAT):268 MG/KG
CAS:121-14-2
RTECS #:XT1575000
Fraction by Wt: 0.1%
OSHA PEL:S, 1.5 MG/,M3
ACGIH TLV:0.15 MG/M3, A2
EPA Rpt Qty:10 LBS
DOT Rpt Qty:10 LBS

Ingred Name:1,3-BUTADIENE, HEXACHLORO-; (HEXACHLOROBUTADIENE) (SARA
    313) (CERCLA) LD50(ORAL,RAT):82 MG/KG
CAS:87-68-3
RTECS #:EJ0700000
Fraction by Wt: 0.1%
OSHA PEL:0.02 PPM
ACGIH TLV:S, 0.02 PPM, A2
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB

Ingred Name:BENZENE, NITRO-; (NITROBENZENE) (SARA 302/313)
    LD50(ORAL,RAT):780 MG/KG
CAS:98-95-3
RTECS #:DA6475000
Fraction by Wt: 0.1%
OSHA PEL:S, 1 PPM
ACGIH TLV:S, 1 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:ACETONE; (2-PROPANONE) (SARA 313) (CERCLA)
    LD50(ORAL,RAT):9750 MG/KG
CAS:67-64-1
RTECS #:AL3150000
Fraction by Wt: 99-100%
OSHA PEL:1000 PPM
ACGIH TLV:750 PPM/1000 STEL
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS

Ingred Name:PYRIDINE (SARA 313) (CERCLA) LD50(ORAL,RAT):891 MG/KG
CAS:110-86-1
RTECS #:UR8400000
Fraction by Wt: 0.1%
OSHA PEL:5 PPM
ACGIH TLV:5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS

Ingred Name:EXPLAN OF CARCIN:TO BE CARCIN. HEXACHLOROBENZENE:IARC
    MONOGRAPHS, SUPP, VOL 7, PG 219, 1987:GROUP 2B. NTP 7TH (ING 10)
RTECS #:9999999ZZ

Ingred Name:ING 9:ANNUAL REPORT ON CARCINOGENS, 1994:ANTICIPATED TO BE
    CARCINOGEN.
RTECS #:9999999ZZ

=====================  Hazards Identification  =====================

LD50 LC50 Mixture:SEE INGREDIENTS
Routes of Entry: Inhalation:YES  Skin:YES  Ingestion:YES
Reports of Carcinogenicity:NTP:YES    IARC:YES	  OSHA:NO
Health Hazards Acute and Chronic:BURNS EYES, IRRITATES RESPIRATORY
    TRACT, CONTAINS MATERIAL(S) KNOWN TO THE STATE OF CALIFORNIA TO
    CAUSE CANCER. LOW BLOOD PRESSURE (HYPOTENSION). IRRITATES SKIN,
    DERMATITIS, IRRITATES NOSE AND THROAT,  HEADACHE, DIZZINESS,
    GASTROINTESTINAL DISTURBANCES, DEPRESSES CENTRAL NERVOUS SYSTEM,
    CONVULSIONS, (EFTS OF OVEREXP)
Explanation of Carcinogenicity:P-DICHLOROBENZENE:IARC MONOGRAPHS, SUPP,
    VOL 7, PG 192, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS.
    1994:ANTIC (ING 9)
Effects of Overexposure:HLTH HAZS:NARCOSIS, COMA, LIVER DAMAGE, KIDNEY
    DAMAGE, REPORTED ANIMAL CARCINOGEN. CARCINOGENICITY:INDEFINITE IN
    MAN. RESPIRATORY FAILURE, ERYTHEMA, ECZEMA, CONJUNCTIVITIS, AND
    CORNEAL EROSION. MAY CA USE CORNEAL INJURY.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

=======================  First Aid Measures  =======================

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. CONT MD. SKIN:PROMPTLY
    WASH W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG.
    INHAL:IMMED MOVE TO FRESH AIR. GIVE OXYG IF BRTHG IS LABORED. IF
    BRTHG STOPS, GIVE  ARTF RESP. CONT MD. INGEST:NEVER GIVE ANYTHING
    BY MOUTH TO AN UNCON PERSON. NEVER TRY TO MAKE UNCON PERSON VOMIT.
    GIVE LG AMTS OF WATER. PRESS FINGERS TO BACK OF TONGUE TO INDUCE
    VOMIT. GIVE (SUPDAT)

=====================  Fire Fighting Measures  =====================

Flash Point Method:CC
Flash Point:-2F,-19C
Lower Limits:2.6%
Upper Limits:13.%
Extinguishing Media:DRY CHEMICAL, ALCOHOL FOAM. WATER MAY BE
    INEFFECTIVE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL
    PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPS FOR EXPLO MIX W/AIR. CNTNRS MAY
    EXPLODE UNDER FIRE CNDTNS. FOLLOWING TOX VAPS ARE FORMED WHEN MATL
    IS HEATED TO DECOMP. OXIDES, OF NITROGEN, (SUPP DATA)

==================  Accidental Release Measures  ==================

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
    AREA. ELIMINATE ALL IGNITION SOURCES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

======================	Handling and Storage  ======================

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINERS. KEEP
    AWAY FROM IGNITION SOURCES.
Other Precautions:AVOID EYE OR SKIN CONTACT. AVOID BREATHING VAPORS.

=============  Exposure Controls/Personal Protection  =============

Respiratory Protection:WEAR NIOSH/MSHA APPROVED SELF CONTAINED
    BREATHING APPARATUS.
Ventilation:USE ONLY IN EXHAUST HOOD.
Protective Gloves:WEAR BUTYL RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
    SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE/PART NO:1X1ML, ACET 1000U. EXPLO HAZS:HYDROGEN CHLORIDE,
    CYANIDE. MATLS TO AVOID:HALOGENS, ALDEHYDES, AMMONIA & CHLORINATED
    CMPDS. FIRST AID PROC:SYRUP OF IPECAC. IMMEDIATELY CONTACT A PHYSI
    CIAN.

==================  Physical/Chemical Properties  ==================

Boiling Pt:B.P. Text:133F,56C
Melt/Freeze Pt:M.P/F.P Text:-139F,-95C
Vapor Pres:181 @ 20C
Vapor Density:2
Spec Gravity:0.792 (H*2O=1)
Evaporation Rate & Reference:14.4 (BUTYL ACETATE=1)
Solubility in Water:100
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:1

=================  Stability and Reactivity Data  =================

Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, OXIDIZING AGENTS, AMINES, OXYG, FLUORINE,
    CHLORINE & BROMINE. ALKANOLAMINES, (SUPP DATA)
Hazardous Decomposition Products:OXIDES OF NITROGEN, HYDROGEN CHLORIDE,
    CYANIDE.

====================  Disposal Considerations  ====================

Waste Disposal Methods:COMPLY WITH ALL FEDERAL, STATE OR LOCAL
    REGULATIONS. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN
    EMPTIED. EMPTIED CONTAINERS RETAIN PRODUCT RESIDUES:HANDLE AS IF
    THEY WERE FULL.

 Disclaimer (provided with this information by the compiling agencies):
 This information is formulated for use by elements of the Department
 of Defense.  The United States of America in no manner whatsoever,
 expressly or implied, warrants this information to be accurate and
 disclaims all liability for its use.  Any person utilizing this
 document should seek competent professional advice to verify and
 assume responsibility for the suitability of this information to their
 particular situation.